Radical-Mediated Heck-Type Alkylation: Stereoconvergent Synthesis of Functionalized Polyenes.
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DOI: 10.1021/acs.orglett.9b02838
Abstract: The stereospecific synthesis of polyenes is of great synthetic value. Disclosed herein is a new, efficient, stereoconvergent approach for the synthesis of functionalized polyenes via a radical-mediated Heck-type alkylation. The easily accessed Z- and E-mixed… read more here.
Keywords: synthesis functionalized; heck type; radical mediated; functionalized polyenes ... See more keywords