Vinyl‐Functionalized Silsesquioxanes and Germasilsesquioxanes
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700465
Abstract: We report herein an efficient procedure for the synthesis of new POSS derivatives, as a multifunctional reagents. This study concerns the incompletely condensed silsesquioxanes and germasilsesqiuoxanes with vinylsubstituted silyl and germyl functional groups which allow… read more here.
Keywords: functionalized silsesquioxanes; silsesquioxanes germasilsesquioxanes; chemistry; vinyl functionalized ... See more keywords
Comparing amine- and ammonium functionalized silsesquioxanes for large scale synthesis of hybrid polyimide high-temperature gas separation membranes
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Membrane Science"
DOI: 10.1016/j.memsci.2021.119524
Abstract: Abstract PolyPOSS-imide membranes are promising for separating H2 from larger molecules (CO2, N2, CH4) at temperatures up to 300 °C. Their fabrication involves two steps: interfacial polymerization of POSS and 6FDA, followed by thermal imidization. This… read more here.
Keywords: gas; functionalized silsesquioxanes; comparing amine; ammonium functionalized ... See more keywords
Catalytic Approach to Germanium-Functionalized Silsesquioxanes and Germasilsesquioxanes
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00599
Abstract: Silsesquioxanes have attracted considerable attention in recent years due to their unique hybrid structure and versatile properties. Herein, we report the first catalytic approach to the synthesis of completely and partially condensed germanium-functionalized silsesquioxanes as… read more here.
Keywords: germanium functionalized; germanium; approach germanium; functionalized silsesquioxanes ... See more keywords