Fundamental Insights into the Reactivity and Utilization of Open Metal Sites in Cu(I)-MFU-4l
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00351
Abstract: Metal–organic frameworks (MOFs) having open metal sites have the potential to approach the activity of homogeneous organometallic complexes, thus combining the advantages of homogeneous and heterogeneous catalysis. We present a fundamental study of the effectiveness… read more here.
Keywords: metal; sites mfu; open metal; insights reactivity ... See more keywords
Fundamental Insights into Deactivation by Leaching during Rhenium-Catalyzed Deoxydehydration
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DOI: 10.1021/acscatal.9b02806
Abstract: Deoxydehydration, a transformation that selectively converts diols into olefins in a single catalytic step, has great potential for biomass upgrading because it removes oxygen, and the obtained double bond is useful for further functionalization. Recent… read more here.
Keywords: deactivation leaching; deoxydehydration; fundamental insights; insights deactivation ... See more keywords
Recent trends and fundamental insights in the methanol-to-hydrocarbons process
Sign Up to like & getrecommendations! Published in 2018 at "Nature Catalysis"
DOI: 10.1038/s41929-018-0078-5
Abstract: The production of high-demand chemical commodities such as ethylene and propylene (methanol-to-olefins), hydrocarbons (methanol-to-hydrocarbons), gasoline (methanol-to-gasoline) and aromatics (methanol-to-aromatics) from methanol—obtainable from alternative feedstocks, such as carbon dioxide, biomass, waste or natural gas through the… read more here.
Keywords: methanol hydrocarbons; trends fundamental; process; recent trends ... See more keywords