Efficient Electrooxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid in a Weak Alkaline Medium Enabled by Interfacial OH− Enrichment
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202502081
Abstract: Developing electrooxidation of 5‐hydroxymethylfurfural (HMF) to 2,5‐furandicarboxylic acid (FDCA) in a weak alkaline medium can potentially inhibit HMF degradation to humins and thus mitigate carbon loss that is encountered in strong alkaline media; however, the… read more here.
Keywords: alkaline medium; electrooxidation hydroxymethylfurfural; furandicarboxylic acid; weak alkaline ... See more keywords
Preparation and performance exploration of 2,5‐furandicarboxylic acid‐based copolyester bioplastics: Controlling thermal properties, tensile properties, and surface hydrophilicity through composition
Sign Up to like & getrecommendations! Published in 2024 at "Journal of Applied Polymer Science"
DOI: 10.1002/app.55835
Abstract: To improve the comprehensive properties of polybutylene furandicarboxylate (PBF), 2,5‐furandicarboxylic acid (2,5‐FDCA), and aliphatic chain diol 1,8‐octanediol and 1,4‐butanediol were used as monomers to synthesize a series of bio‐based polybutylene glycol‐octanediol 2,5‐furandicarboxylate (PBOF). The results… read more here.
Keywords: composition; pbof; copolyester; preparation performance ... See more keywords
Chemocatalytic Oxidation of 5‐hydroxymethylfurfural into 2,5‐furandicarboxylic Acid Over Nickel Cobalt Oxide
Sign Up to like & getrecommendations! Published in 2024 at "ChemCatChem"
DOI: 10.1002/cctc.202400973
Abstract: The present study reports the synthesis, characterization, and application of NiCo bimetallic catalysts to produce 2,5‐furandicarboxylic acid (FDCA) via the oxidation of bio‐renewable 5‐hydroxymethylfurfural (HMF). FDCA is a biopolymer precursor and a potential replacement for… read more here.
Keywords: oxidation hydroxymethylfurfural; chemocatalytic oxidation; hydroxymethylfurfural furandicarboxylic; acid ... See more keywords
Enhanced Electrocatalytic Oxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid via N‐Hydroxyphthalimide‐Integrated Porphyrin(Co) Covalent Organic Frameworks
Sign Up to like & getrecommendations! Published in 2025 at "ChemCatChem"
DOI: 10.1002/cctc.202401674
Abstract: The depletion of fossil fuel reserves, coupled with the mounting environmental concerns, highlights the urgent need to develop sustainable methods for chemical synthesis from renewable resources. One promising avenue is the electrocatalytic oxidation of 5‐hydroxymethylfurfural… read more here.
Keywords: por cof; oxidation hydroxymethylfurfural; covalent organic; organic frameworks ... See more keywords
Self‐Supported Ru‐CoFe Prussian Blue Analogues for Selective and Scalable Electrooxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid
Sign Up to like & getrecommendations! Published in 2025 at "ChemCatChem"
DOI: 10.1002/cctc.202501428
Abstract: The electrochemical upgrading of biomass‐derived 5‐hydroxymethylfurfural (HMF) into 2,5‐furandicarboxylic acid (FDCA) represents a promising route for producing renewable monomers for biodegradable plastics. However, achieving high conversion and selectivity under industrially relevant conditions remains challenging due… read more here.
Keywords: prussian blue; hmf; cofe prussian; furandicarboxylic acid ... See more keywords
Highly effective non-noble MnO2 catalysts for 5-hydroxymethylfurfural oxidation to 2,5-furandicarboxylic acid.
Sign Up to like & getrecommendations! Published in 2024 at "ChemSusChem"
DOI: 10.1002/cssc.202400115
Abstract: Noble metal-free catalyst or catalytic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid are proposed in this study as a proposal to solve one of the great disadvantages of this reaction of using preferably noble metal-based catalysts.… read more here.
Keywords: effective non; mno2; highly effective; non noble ... See more keywords
Multistep Biooxidation of 5-(Hydroxymethyl)furfural to 2,5-Furandicarboxylic Acid with H2O2 by Unspecific Peroxygenases.
Sign Up to like & getrecommendations! Published in 2024 at "ChemSusChem"
DOI: 10.1002/cssc.202400156
Abstract: 5-(Hydroxymethyl)furfural (HMF) is a key platform chemical derived from renewable biomass sources, holding great potential as starting material for the synthesis of valuable compounds, thereby replacing petrochemical-derived counterparts. Among these valorised compounds, 2,5-furandicarboxylic acid (FDCA)… read more here.
Keywords: hydroxymethyl furfural; multistep biooxidation; hmf; unspecific peroxygenases ... See more keywords
Furandicarboxylic Acid (FDCA): Electrosynthesis and Its Facile Recovery From Polyethylene Furanoate (PEF) via Depolymerization
Sign Up to like & getrecommendations! Published in 2024 at "Chemsuschem"
DOI: 10.1002/cssc.202401190
Abstract: Abstract Replacing fossil fuels with renewable, bio‐based alternatives is inevitable for the modern chemical industry, in line with the 12 principles of green chemistry. 2,5‐Furandicarboxylic acid (FDCA) is a promising platform molecule that can be… read more here.
Keywords: pef; furanoate pef; depolymerization; acid fdca ... See more keywords
Efficient Integration of 5‐Hydroxymethylfurfural Oxidation to 2,5‐Furandicarboxylic Acid with Electrochemical Reduction of CO2 to Tunable Syngas Production in a Flow Cell
Sign Up to like & getrecommendations! Published in 2025 at "Chemsuschem"
DOI: 10.1002/cssc.202502122
Abstract: Pairing electrochemical CO2 reduction (CO2RR) with the oxygen evolution reaction (OER) significantly limits overall system efficiency due to the high energy demand of the OER and low product value. Here, a scalable electrochemical platform is… read more here.
Keywords: efficiency; co2; syngas production; flow cell ... See more keywords
Metal-Organic Frameworks (MOFs)-Derived Mesoporous Carbon Encapsulated Ultrafine Scandium Oxide Electrocatalyst for Highly Efficient Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid.
Sign Up to like & getrecommendations! Published in 2025 at "Small methods"
DOI: 10.1002/smtd.202500187
Abstract: Green electrochemical synthesis of 2,5-furandicarboxylic acid (FDCA) from biomass is an essential alternative for the substitution of petroleum-based terephthalic acid. The rational design and application of high-performance electrocatalysts are the key to advance this technique.… read more here.
Keywords: mesoporous carbon; carbon encapsulated; electrocatalyst; oxidation ... See more keywords
Synthesis and properties of polyamides from 2,5-furandicarboxylic acid and aromatic and aliphatic diamines
Sign Up to like & getrecommendations! Published in 2020 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-020-2770-2
Abstract: Polyamides based on the 5-hydroxymethylfurfural derivative (2,5-furandicarboxylic acid dichloroanhydride) and diamines of both aromatic and aliphatic series were synthesized. The reactions were monitored by 1 H NMR and IR spectroscopy. The thermal stability, glass transition… read more here.
Keywords: acid aromatic; aromatic aliphatic; furandicarboxylic acid; synthesis properties ... See more keywords