Pd/Cu-MOF as a highly efficient catalyst for synthesis of cyclopentanone compounds from biomass-derived furanic aldehydes
Sign Up to like & getrecommendations! Published in 2019 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2019.04.008
Abstract: Abstract Herein, a series of Pd nanoparticles supported on Cu-MOFs (Cu3(BTC)2, FeCu-DMC) with pure Lewis acidity are synthesized for hydrogenative ring-rearrangement reaction of furanic aldehydes (furfural, 5-hydroxymethyl furfural) to cyclopentanone compounds (cyclopentanone, 3-hydroxymethyl cyclopentanone). For… read more here.
Keywords: furanic aldehydes; fecu dmc; cyclopentanone compounds; mof highly ... See more keywords
Double-metal cyanide-supported Pd catalysts for highly efficient hydrogenative ring-rearrangement of biomass-derived furanic aldehydes to cyclopentanone compounds
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2019.08.036
Abstract: Abstract The hydrogenative ring-rearrangement of biomass-derived furanic aldehydes (furfural or 5-hydroxymethyl furfural) to cyclopentanone compounds (cyclopentanone or 3-hydroxymethyl cyclopentanone) is of great significance for high-value chemicals. The Bronsted acid in metal-support bifunctional catalysts causes a… read more here.
Keywords: cyclopentanone compounds; cyclopentanone; biomass; furanic aldehydes ... See more keywords
Reductive Amination of Furanic Aldehydes in Aqueous Solution over Versatile NiyAlOx Catalysts
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DOI: 10.1021/acsomega.8b03516
Abstract: We disclose in this study a Ni6AlOx catalyst prepared by coprecipitation for the reductive amination of biomass-derived aldehydes and ketones in aqueous ammonia under mild reaction conditions. The catalyst exhibited 99% yield toward 5-aminomethyl-2-furylmethanol in… read more here.
Keywords: furanic aldehydes; reductive amination; amination furanic; amination ... See more keywords