Mechanistic studies on the in-situ generation of furoxan ring during the formation of Cu(II) coordination compound from dioxime ligand: Theoretical and experimental study
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119756
Abstract: Abstract The copper(II) coordination compound, [Cu(Lʹ)(NO3)2] (1) where Lʹ = 3,4-di(pyridin-2-yl)-1,2,5-oxadiazole 2-oxide, was synthesized from the reaction of Cu(NO3)2·3H2O and dioxime ligand, (1E,2E)-1,2-di(pyridin-2-yl)ethane-1,2-dione dioxime (L), in methanol under aerial atmosphere. The dark-blue crystals of 1… read more here.
Keywords: furoxan ring; formation; dioxime; compound ... See more keywords
Direct introduction of cyano group on furoxan ring
Sign Up to like & getrecommendations! Published in 2017 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2017.11.008
Abstract: Potassium cyanide reacts with 3-aryl-4-phenylsulfonylfuroxan/ furazan under mild conditions in DMF at room temperature in the presence of 18-crown-6 to afford 3-aryl-4-cyanofuroxan/ furazan in 45–50% yield. read more here.
Keywords: furoxan ring; cyano group; introduction cyano; group furoxan ... See more keywords