Fully fused boron-doped polycyclic aromatic hydrocarbons: their synthesis, structure–property relationships, and self-assembly behavior in aqueous media
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d1sc06710a
Abstract: Planarized triarylboranes are attracting increasing attention not only as models of boron-doped graphenes, but also as promising materials for organic optoelectronics. In particular, polycyclic aromatic hydrocarbon (PAH) skeletons with embedded boron atom(s) in the inner… read more here.
Keywords: fused boron; polycyclic aromatic; boron; synthesis ... See more keywords
Photoinduced boron atom insertion of benzocyclobutene forming an unprecedented fused boron heterocyclic radical.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06566e
Abstract: Two novel boron heterocyclic radicals, an addition bicyclo[4.2.1]octa-1,3,5-trien-1-yl-borane radical (A) and an insertion 7-1H-borolo[1,2-a]borinine radical (B), were synthesized, and characterized in the reaction of atomic boron with benzocyclobutene. Species B involving a fused boron heterocyclic… read more here.
Keywords: fused boron; boron; insertion; photoinduced boron ... See more keywords