Ring-fused hexahydro-1,2,4,5-tetrazines: synthesis, structure, and mechanistic studies on isolable rotational isomers.
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DOI: 10.1039/d2cc06170h
Abstract: We designed conformationally stable rotational isomers around the C(sp2)-C(sp3) axis at the C3-position of hexahydro-1,2,4,5-tetrazines. Isolation of each rotamer by silica gel column chromatography was successfully achieved at room temperature. The proposed isomerization mechanism of… read more here.
Keywords: ring fused; hexahydro tetrazines; rotational isomers; fused hexahydro ... See more keywords