Electronic and mechanistic insights into the role of group 15 elements in the reactivity of dipnictogen dications featuring group 15group 15 double bonds in [2 + 2] cycloaddition reactions with phenylacetylene.
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DOI: 10.1039/d5dt01453k
Abstract: A computational study at the M06-2X-D3/def2-TZVP level elucidates the [2 + 2] cycloaddition between phenylacetylene and G15-Rea ((L: → G15G15 ← :L)2+), featuring a doubly bonded G15G15 moiety (G15 = a group 15 element) and… read more here.
Keywords: g15 rea; double bonds; dipnictogen dications; group ... See more keywords