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Published in 2019 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.01.005
Abstract: Abstract A novel synthetic route towards two series of enantiomerically pure cyclic analogues of 2,3-cis- and 2,3-trans-γ-aminobutyric acid (GABA) was developed. The route is based on the elongation and stereodivergent manipulation of a readily accessible…
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Keywords:
gaba;
acid gaba;
route;
aminobutyric acid ... See more keywords
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Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b02320
Abstract: Water enables the highly challenging enantioselective Michael addition of sterically congested β-trifluoromethyl-β-aryl- or -alkyl-substituted nitroolefins with dithiomalonates. Under on-water conditions, the reaction rates were remarkably accelerated as a result of enforced hydrophobic interactions between catalysts…
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Keywords:
water;
michael;
gaba analogues;
access chiral ... See more keywords