Unravelling the Potential of Ylides in Stabilizing Low-Valent Group 13 Compounds: Theoretical Predictions of Stable, Five-Membered Group 13 (Aluminum and Gallium) Carbenoids Capable of Small-Molecule Activation.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01630
Abstract: Computational investigations provide evidence toward the remarkable ability of strongly electron-donating ylidic functionalities in stabilizing singlet group 13 carbenoids with promising ligand properties. All of the proposed carbenoids are found to be considerably nucleophilic and… read more here.
Keywords: small molecule; aluminum gallium; gallium carbenoids; group ... See more keywords
Skeletally Substituted Aluminium and Gallium Carbenoids: A Computational Exploration
Sign Up to like & getrecommendations! Published in 2023 at "Dalton Transactions"
DOI: 10.1039/d3dt00631j
Abstract: Comprehensive computational investigations were carried out to understand the electronic and ligand properties of skeletally substituted β-diketiminate stabilized Al(I) and Ga(I) carbenoids as well as to probe their potential in... read more here.
Keywords: skeletally substituted; carbenoids computational; gallium carbenoids; computational exploration ... See more keywords