Control of gate adsorption characteristics of flexible metal-organic frameworks by crystal defect
Sign Up to like & getrecommendations! Published in 2020 at "Microporous and Mesoporous Materials"
DOI: 10.1016/j.micromeso.2020.110215
Abstract: Abstract Flexible metal-organic frameworks (flexible MOFs) are known to exhibit a step-wise adsorption behavior induced by structural transition. This adsorption behavior is referred to as the “gate” adsorption behavior as it resembles the opening and… read more here.
Keywords: adsorption; crystal defect; gate adsorption; adsorption behavior ... See more keywords
Liquid/vapor-induced reversible dynamic structural transformation of a three-dimensional Cu-based MOF to a one-dimensional MOF showing gate adsorption.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01126a
Abstract: A new 3D metal-organic framework (MOF), in which 2D layers are interlaced to form a 3D architecture, was synthesized by a reaction of Cu(BF4)2 and 1,3-bis(4-pyridyl)propane (bpp) in a water/1-hexanol solvent system, and the crystal… read more here.
Keywords: vapor induced; adsorption; mof; gate adsorption ... See more keywords