Nature and origin of γ-gauche effect in sulfoxides: A density functional theory and information-theoretic approach study
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DOI: 10.1016/j.cplett.2019.06.039
Abstract: Abstract Bulky vicinal groups around a single bond usually prefer to be in the opposite (anti) conformation but when extra interactions come into play, more stable could be the gauche conformer, where the neighboring groups… read more here.
Keywords: gauche effect; gauche; theory; density functional ... See more keywords