[PtZn2Ge18(Hyp)8] (Hyp = Si(SiMe3)3): A Neutral Polynuclear Chain Compound with Ge9(Hyp)3 Units.
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DOI: 10.1021/acs.inorgchem.8b01757
Abstract: The reaction of [ZnGe18(Hyp)6] (Hyp = Si(SiMe3)3) with Pt(PPh3)4 gives the neutral polynuclear complex of Ge9(Hyp)3 units [HypZn-Ge9(Hyp)3-Pt-Ge9(Hyp)3-ZnHyp], 1. Within 1, the central Pt atom is bound η3 to both Ge9(Hyp)3 units to which further… read more here.
Keywords: hyp hyp; hyp units; ge9 hyp; hyp ... See more keywords
Zintl cluster supported low coordinate Rh(i) centers for catalytic H/D exchange between H2 and D2
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DOI: 10.1039/d2sc02552c
Abstract: Ligand exchange reactions of [Rh(COD){η4-Ge9(Hyp)3}] with L-type nucleophiles such as PMe3, PPh3, IMe4 (IMe4 = 1,3,4,5-tetramethylimidazol-2-ylidene) or [W(Cp)2H2] result in the displacement of the COD ligand to afford clusters with coordinatively unsaturated trigonal pyramidal rhodium(i)… read more here.
Keywords: supported low; exchange; zintl cluster; cluster supported ... See more keywords