Articles with "gel promoted" as a keyword



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Silica gel-promoted synthesis of multisubstituted spiroindolenines from tryptamines and γ-chloro-α,β-unsaturated ketones

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Published in 2021 at "Tetrahedron"

DOI: 10.1016/j.tet.2020.131765

Abstract: ABSTRACT Here we report a one-pot synthesis of multisubstituted spiroindolenines from a series of tryptamine derivatives with γ-chloro-α,β-unsaturated ketones. The reaction sequence consists of base-induced condensation and silica gel-promoted intramolecular Michael addition. The target molecules… read more here.

Keywords: unsaturated ketones; synthesis multisubstituted; multisubstituted spiroindolenines; chloro unsaturated ... See more keywords
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A Mild Silica Gel Promoted Synthesis and Initial Functional Study of Tetrapyridyl Tetrahydropyrrolopyrrolones.

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Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c02095

Abstract: A one-pot strategy with yields up to 82% was reported to generate 2-(pyridin-2-yl)-2-(3,3a,6-tris(5-pyridin-2-yl)-5-oxohexahydropyrrolo[3,2-b] pyrrol-2(1H)-ylidene)acetonitrile 1a and its derivatives 1b-d. Silica gel promoted quantitative conversion from stable intermediate to 1a within 30 min at room temperature.… read more here.

Keywords: mild silica; initial functional; gel promoted; synthesis initial ... See more keywords