Design, synthesis, and rearrangement studies of gem-dimethyl containing cage systems
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DOI: 10.1016/j.tet.2019.130898
Abstract: Abstract A variety of functionalized cage compounds and D3-trishomocubane derivatives have been assembled via the Diels–Alder strategy, with reductive cleavage of the cyclopropane ring and metal promoted ring rearrangement as key steps. We have installed… read more here.
Keywords: design synthesis; containing cage; cage systems; gem dimethyl ... See more keywords
Exploring the gem-dimethyl effect in the formation of imine-based macrocycles and cages
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DOI: 10.1039/c7nj02069d
Abstract: Using the gem-dimethyl effect as a platform, a variety of organic [2+2] macrocycles and [2+3] cofacial cages was obtained in high yields. Imine-based macrocyclization could be performed even at high concentrations (0.5 to 1.0 M),… read more here.
Keywords: imine based; dimethyl effect; gem dimethyl;