General Light-Mediated, Highly Diastereoselective Piperidine Epimerization: From Most Accessible to Most Stable Stereoisomer.
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DOI: 10.1021/jacs.0c11911
Abstract: We report a combined photocatalytic and hydrogen atom transfer (HAT) approach for the light-mediated epimerization of readily accessible piperidines to provide the more stable diastereomer with high selectivity. The generality of the transformation was explored… read more here.
Keywords: general light; light mediated; epimerization; mediated highly ... See more keywords