Vinyl Carbocations Generated under Basic Conditions and Their Intramolecular C-H Insertion Reactions.
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DOI: 10.1021/jacs.9b02110
Abstract: Here we report the surprising discovery that high-energy vinyl carbocations can be generated under strongly basic conditions, and that they engage in intramolecular sp3 C-H insertion reactions through the catalysis of weakly coordinating anion salts.… read more here.
Keywords: insertion reactions; insertion; generated basic; basic conditions ... See more keywords