Generating Fischer-Type Rh-Carbenes with Rh-Carbynoids
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DOI: 10.1021/jacs.3c00012
Abstract: We describe the first catalytic generation of Fischer-type acyloxy Rh(II)-carbenes from carboxylic acids and Rh(II)-carbynoids. This novel class of transient donor/acceptor Rh(II)-carbenes evolved through a cyclopropanation process providing access to densely functionalized cyclopropyl-fused lactones with… read more here.
Keywords: carbenes carbynoids; type carbenes; generating fischer; fischer type ... See more keywords