An enantioselective cascade for simultaneous generation of five quaternary stereocenters from fully substituted enones.
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DOI: 10.1039/c7cc03995f
Abstract: A highly enantioselective cascade reaction for the generation of five quaternary stereocenters in one-pot operation is reported for the first time in the history of organic synthesis. Cinchona-alkaloid derived hydrogen-bonding catalyst furnished structurally complex cascade… read more here.
Keywords: quaternary stereocenters; five quaternary; cascade simultaneous; generation five ... See more keywords