Generation of a Ni3 Phosphinidene Cluster from the Ni(0) Synthon, Ni(η3-CPh3)2
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DOI: 10.1021/acs.organomet.0c00095
Abstract: Reaction of NiCl2 in THF with 2 equiv of Li(CPh3) at −25 °C results in formation of Ni(η3-CPh3)2 (1) in moderate yield. Complex 1 was fully characterized, which included analysis by X-ray crystallo... read more here.
Keywords: phosphinidene cluster; cph3; generation ni3; ni3 phosphinidene ... See more keywords