Nucleation as a rate-determining step in catalytic gas generation reactions from liquid phase systems
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DOI: 10.1126/sciadv.ade3262
Abstract: The observable reaction rate of heterogeneously catalyzed reactions is known to be limited either by the intrinsic kinetics of the catalytic transformation or by the rate of pore and/or film diffusion. Here, we show that… read more here.
Keywords: gas generation; nucleation; generation reactions; rate ... See more keywords
Generation and Reactions of ε-Carbonyl Cations via Group 13 Catalysis
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DOI: 10.3390/molecules27103078
Abstract: The generation of ε-carbonyl cations and their reactions with nucleophiles is accomplished readily without transition metal cation stabilization, using the ε-bromide dienoate or dienone starting materials and GaCl3 or InCl3 catalysis. Arene nucleophiles are somewhat… read more here.
Keywords: carbonyl cations; catalysis; reactions carbonyl; cations via ... See more keywords