Nitrogen-Centered Radicals in Functionalization of sp2 Systems: Generation, Reactivity, and Applications in Synthesis.
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DOI: 10.1021/acs.chemrev.1c00831
Abstract: The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic synthesis, and they continue to expand as our understanding of these reactive species increases. The utility of these reactive intermediates is demonstrated in the… read more here.
Keywords: functionalization sp2; functionalization; synthesis; generation reactivity ... See more keywords
Theoretical insights into the generation and reactivity of hydride on the ZnO(101̄0) surface
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DOI: 10.1039/d4sc04344h
Abstract: ZnO is an important catalytic material for CO/CO2 hydrogenation. In this work, the pristine ZnO(101̄0) and the surfaces with Zn–O dimer vacancies (ZnO(101̄0)–(Zn–O)DiV) and oxygen vacancies are calculated. We find that the hydride (H−) species… read more here.
Keywords: theoretical insights; reactivity hydride; hydride zno; insights generation ... See more keywords