Distinctive Aspects in Aquation, Proton-Coupled Redox, and Photoisomerization Reactions between Geometric Isomers of Mononuclear Ruthenium Complexes with a Large-π-Conjugated Tetradentate Ligand.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01937
Abstract: Geometric isomers of mononuclear ruthenium(II) complexes, distal-/proximal-[Ru(tpy)(dpda)Cl]+ (d-/p-RuCl, tpy = 2,2':6',2″-terpyridine, dpda = 2,7-bis(2-pyridyl)-1,8-diazaanthracene), were newly synthesized to comprehensively investigate the geometric and electronic structures and distinctive aspects in various reactions between isomers. The ultraviolet… read more here.
Keywords: ruthenium complexes; mononuclear ruthenium; dpda; geometric isomers ... See more keywords
Adsorptive Separation of Geometric Isomers of 2-Butene on Gallate-Based Metal-Organic Frameworks.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.9b20092
Abstract: The separation of mixed C4-olefins is a highly energy-intensive operation in the chemical industry due to the close boiling points of the unsaturated C4 isomers. In particular, the separation of trans/cis-2-butene is among the most… read more here.
Keywords: gallate based; butene; trans cis; separation ... See more keywords
Geometric Isomers of Asymmetric Rigid Four-Membered Chelating Ring Based Deep-Red-Emitting Iridium Complexes Featuring Three Charged (0, -1, -2) Ligands
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic Chemistry Frontiers"
DOI: 10.1039/d3qi00224a
Abstract: Geometric isomers are very important and interesting in the field of optical materials. In this work, we have designed and synthesized a new series of geometric isomers of iridium complexes... read more here.
Keywords: rigid four; iridium complexes; asymmetric rigid; four membered ... See more keywords