Reaction Site Designation by Intramolecular Electric Field in Tröger's‐Base‐Derived Conjugated Microporous Polymer for Near‐Unity Selectivity of CO2 Photoconversion
Sign Up to like & getrecommendations! Published in 2023 at "Advanced Materials"
DOI: 10.1002/adma.202210693
Abstract: To facilitate solar‐driven overall CO2 and H2O convsersion into fuels and O2, a series of covalent microporous polymers derived from Tröger's base are synthesized featuring flexural backbone and unusual charge‐transfer properties. The incorporation of rigid… read more here.
Keywords: reaction; ger base; co2; base ... See more keywords
Design, Synthesis, and Anticancer Studies of a p-Cymene-Ru(II)-Curcumin Organometallic Conjugate Based on a Fluorescent 4-Amino-1,8-naphthalimide Tröger's Base Scaffold.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01005
Abstract: A unique V-shaped "chiral" supramolecular scaffold, N-(4-pyridyl)-4-amino-1,8-naphthalimide Tröger's base (TBNap), was synthesized in good yield from a precursor N-(4-pyridyl)-4-amino-1,8-naphthalimide (Nap). TBNap was characterized using different spectroscopic methods and the molecular structure was elucidated by diffraction… read more here.
Keywords: amino naphthalimide; naphthalimide ger; cymene curcumin; amino ... See more keywords
Proton Conduction in Tröger's Base-Linked Poly(crown ether)s.
Sign Up to like & getrecommendations! Published in 2018 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.8b05532
Abstract: Exactly 50 years ago, the ground-breaking discovery of dibenzo[18]crown-6 (DB18C6) by Charles Pedersen led to the use of DB18C6 as a receptor in supramolecular chemistry and a host in host-guest chemistry. We have demonstrated proton… read more here.
Keywords: base linked; ger base; db18c6; chemistry ... See more keywords
Tröger’s Base Network Polymers of Intrinsic Microporosity (TB-PIMs) with Tunable Pore Size for Heterogeneous Catalysis
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c04739
Abstract: Heterogeneous catalysis plays a pivotal role in the preparation of value-added chemicals, and it works more efficiently when combined with porous materials and supports. Because of that, a detailed assessment of porosity and pore size… read more here.
Keywords: pims tunable; tunable pore; heterogeneous catalysis; size ... See more keywords
Supramolecular coordination polymers using a close to 'V-shaped' fluorescent 4-amino-1,8-naphthalimide Tröger's base scaffold.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc07333j
Abstract: A V-shaped 4-amino-1,8-naphthalimide derived dipyridyl ligand comprising the Tröger's base structural motif has been synthesised and subsequently used in the formation of two new supramolecular coordination polymers. read more here.
Keywords: amino naphthalimide; ger base; coordination polymers; supramolecular coordination ... See more keywords
Adjustable chiral self-sorting and self-discriminating behaviour between diamond-like Tröger's base-linked cryptands.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc03577j
Abstract: Two isomers of Tröger's base-linked cryptands 5a and 5b were synthesized, and both of them have two chiral N-centers, exhibiting rare diamond-like scaffolds. Particularly, when growing from the solution of rac-5a, a single enantiomer RNRN-5a… read more here.
Keywords: linked cryptands; base linked; ger base; chiral self ... See more keywords
Selective removal of toxic organic dyes using Trӧger base-containing sulfone copolymers made from a metal-free thiol-yne click reaction followed by oxidation
Sign Up to like & getrecommendations! Published in 2021 at "RSC Advances"
DOI: 10.1039/d1ra03783h
Abstract: Copolymers TCP1–3 with Trӧger's base units and aryl thioether groups were made via a click reaction. Selective oxidation of the thioethers into sulfone groups afforded TCP4–6 which display up to 100% removal efficiency of methylene… read more here.
Keywords: selective removal; ger base; click reaction;
The synthesis, characterization and carbon dioxide adsorption of polyimide aerogels containing Tröger’s base units
Sign Up to like & getrecommendations! Published in 2022 at "High Performance Polymers"
DOI: 10.1177/09540083221115567
Abstract: Microporous polymers with uniform pores and large specific surface areas have been extensively studied in the field of CO2 adsorption and separation. However, the synthesis of these microporous materials is quite complex and difficult to… read more here.
Keywords: adsorption; co2; polyimide aerogels; ger base ... See more keywords
Synthesis and antibacterial activity of spiro[4H-pyran-3,3'-oxindoles] catalyzed by Tröger's base derivative.
Sign Up to like & getrecommendations! Published in 2022 at "Current organic synthesis"
DOI: 10.2174/1570179419666220614142611
Abstract: objective 1. Two class of spiro[4H-pyran-3,3'-oxindole] derivatives were prepared via the one-pot reaction of chain diketones (1-phenyl-1,3-butanedione or dibenzoyl methane), substituted isatins and malononitrile successfully and which effectively catalyzed by a Tröger's base derivative 1b… read more here.
Keywords: spiro pyran; reaction; base derivative; activity ... See more keywords
A Tröger’s Base-Derived Covalent Organic Polymer Containing Carbazole Units as a High-Performance Supercapacitor
Sign Up to like & getrecommendations! Published in 2021 at "Polymers"
DOI: 10.3390/polym13091385
Abstract: Porous organic polymers have been received considerable attention due to their heteroatom-containing structures and high surface areas, which can offer high electrochemical performance in energy applications. The majority of reported Tröger’s base-functionalized porous organic polymers… read more here.
Keywords: ger base; organic polymer; polymer; performance ... See more keywords