Selective recovery of germanium from iron-rich solutions using a supported ionic liquid phase (SILP)
Sign Up to like & getrecommendations! Published in 2019 at "Separation and Purification Technology"
DOI: 10.1016/j.seppur.2019.03.068
Abstract: Abstract A supported ionic liquid phase (SILP) was developed to selectively recover germanium from iron-rich aqueous solutions. The SILP was synthesised by impregnating Amberlite XAD-16N with Aliquat 336, a mixture of quaternary ammonium salts. Characterisation… read more here.
Keywords: germanium; germanium iron; iron rich; ionic liquid ... See more keywords
{Ge8[Fe(CO)4]8}7-: an anionic cubic germanium-iron-cluster featuring an unpaired electron.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01090a
Abstract: Within the reaction of a metastable Ge(I)Cl solution and Na2Fe2(CO)8 the anionic cubic cluster compound {(thf)14Na6Ge8[Fe(CO)4]8}- (3) is obtained. The open shell character of 3 is proven by EPR spectroscopy. Quantum chemical calculations furthermore show… read more here.
Keywords: iron cluster; germanium iron; cubic germanium; cluster ... See more keywords