LAUSR

Alternative Conceptual Approach to the Design of Bifunctional Catalysts: An Osmium Germylene System for the Dehydrogenation of Formic Acid.

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1 Published in 2021 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.1c02893

Abstract: The reaction of the hexahydride OsH6(PiPr3)2 with a P,Ge,P-germylene-diphosphine affords an osmium tetrahydride derivative bearing a Ge,P-chelate, which arises from the hydrogenolysis of a P-C(sp3) bond. This Os(IV)-Ge(II) compound is a pioneering example of a… read more here.

Keywords: dehydrogenation; formic acid; dehydrogenation formic; germylene ... See more keywords

Insertion Reaction of Me3SiN3 with Bis(germylene).

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2 Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c02252

Abstract: Herein, we describe the redox reaction of bis(germylene) PhC(NtBu)2Ge-Ge(NtBu)2CPh with different equivalents of Me3SiN3 affording two distinct products. The reaction of Me3SiN3 with bis-germylene in a 1:1 molar ratio results in compound 1 at -78… read more here.

Keywords: bis germylene; reaction me3sin3; germylene;

Ambiphilic Behavior of Ge(II)-Pseudohalides in Inter- and Intramolecular Frustrated Lewis Pair Alkyne Addition Reactions.

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1 Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c03171

Abstract: The reaction of the germylene chloride (NacNac)GeCl (1, NacNac = CH{(CMe)(2,6-iPr2C6H3N)}2), phenylacetylene, and B(C6F5)3 gives the intermolecular frustrated Lewis pair (FLP) addition product 2. In this case, the Ge(II) center acts as a base. In… read more here.

Keywords: addition; lewis pair; frustrated lewis; c6f5 ... See more keywords

A Two-Coordinate Neutral Germylene Supported by a β-Diketiminate Ligand in the Radical State

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1 Published in 2017 at "Organometallics"

DOI: 10.1021/acs.organomet.7b00400

Abstract: Using the new β-diketimine 1a (PhCH(PhC═N-Dip)2, Dip = 2,6-iPr2C6H3), which possesses three phenyl groups at the ligand backbone, we synthesized the β-diketiminato germylene chloride 2 (LGeCl, L = [PhC(PhCN-Dip)2]−). The β-diketiminato germanium radical complex 3… read more here.

Keywords: neutral germylene; coordinate neutral; two coordinate; dip ... See more keywords