Open-Shell Germylene Stabilized by a Phenalenyl-Based Ligand.
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DOI: 10.1021/acs.inorgchem.3c00583
Abstract: An open-shell germylene 1 stabilized by a phenalenyl-based bidentate ligand was synthesized and characterized. Because of the high thermal stability originating from spin delocalization over the phenalenyl moiety, it was possible to isolate compound 1… read more here.
Keywords: shell germylene; germylene stabilized; stabilized phenalenyl; open shell ... See more keywords
Catalytic cyanosilylation using germylene stabilized platinum(ii) dicyanide.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt00043c
Abstract: The ability of a platinum compound to act as a catalyst for the cyanosilylation of carbonyl compounds is demonstrated through a well-defined germylene stabilized Pt(ii) dicyanide, trans-{(iBu)2ATIGe(iPr)}2Pt(CN)2. read more here.
Keywords: platinum; catalytic cyanosilylation; cyanosilylation using; germylene stabilized ... See more keywords