Hepta-Zr-Incorporated Polyoxometalate Assembly.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01124
Abstract: Driven by the synergistic-directing effect of the lacunary fragments, [B-α-GeW9O34]10- and [B-α-GeW11O39]8-, an unprecedented hepta-Zr-substituted polyoxometalate (POM) assembly K2Na6H10(Hpy)3[SbZr7O6(OH)4(B-α-GeW9O34)2(B-α-GeW11O39)2]·28H2O (1) was made under hydrothermal condition and structurally characterized. Of which, a unique hepta-Zr cluster, [SbZr7O6(OH)4]15+… read more here.
Keywords: incorporated polyoxometalate; gew11o39; hepta; geometry ... See more keywords
Lanthanide-Containing 22-Tungsto-2-germanates [Ln(GeW11O39)2]13-: Synthesis, Structure, and Magnetic Properties.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b03271
Abstract: We report on the synthesis and structural characterization of two series of lanthanide-containing 22-tungsto-2-germanates. The first series corresponds to a family of polyanions with the formula [Ln(β2-GeW11O39)2]13- (LnIII = La (1), Ce (2), Pr (3),… read more here.
Keywords: gew11o39; tungsto germanates; structure; lanthanide containing ... See more keywords