Gibbosolide A, a highly functionalized 20-membered macrolide with a terminal cis-fused 2-methylhexahydro-2H-furo[3,2-b]pyran motif: insights into late-stage cyclization of marine macrolides
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DOI: 10.1039/d1qo01038g
Abstract: The planar structure and absolute configuration of a sailboat-shaped marine macrolide, featuring twelve carbon stereocenters and a cis-fused ether ring juncture, were unambiguously established by a combined approach of chemistry and spectroscopy. read more here.
Keywords: gibbosolide highly; chemistry; cis fused; membered macrolide ... See more keywords