Photoexcited NiII-Aryl Complex-Mediated Giese Reaction of Aryl Bromides.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c01219
Abstract: A Giese reaction of aryl bromides with electron-deficient alkenes was developed, enabled by a dual catalyst system containing NiII complex and IrIII photocatalyst. This protocol could accommodate a variety of aryl bromides and electron-deficient alkenes,… read more here.
Keywords: niii aryl; aryl; reaction aryl; giese reaction ... See more keywords
A Giese reaction for electron-rich alkenes†‡
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc06341j
Abstract: A general method for the hydroalkylation of electron-rich terminal and non-terminal alkenes such as enol esters, alkenyl sulfides, enol ethers, silyl enol ethers, enamides and enecarbamates has been developed. The reactions are carried out at… read more here.
Keywords: rich alkenes; electron rich; reaction electron; giese reaction ... See more keywords