Articles with "glycal cis" as a keyword



Stereoselective Multigram-Scale Tn Antigen Synthesis via the Iron-Catalyzed Glycal 1,2-cis-Aminoglycosylation

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Published in 2025 at "Organic Letters"

DOI: 10.1021/acs.orglett.5c01560

Abstract: We report here a new catalytic and exclusively cis-selective glycosylation strategy for multigram scale synthesis of biologically valuable Tn antigens. The underlying iron-catalyzed glycal 1,2-cis-aminoglycosylation method is effective with a variety of galactosyl donors and… read more here.

Keywords: catalyzed glycal; glycal cis; cis aminoglycosylation; synthesis ... See more keywords