Bismuth-Catalyzed Stereoselective 2-Deoxyglycosylation of Disarmed/Armed Glycal Donors.
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DOI: 10.1021/acs.orglett.1c04008
Abstract: Bi(OTf)3 promoted direct and highly stereoselective glycosylation of "disarmed" and "armed" glycals to synthesize 2-deoxyglycosides has been reported. The tunable and solvent-controlled chemoselective activation of deactivated glycal donors distinguishing the competitive Ferrier and 1,2-addition pathways… read more here.
Keywords: deoxyglycosylation disarmed; disarmed armed; catalyzed stereoselective; stereoselective deoxyglycosylation ... See more keywords