Understanding the Reaction Mechanism of Glycerol Hydrogenolysis over a CuCr2 O4 Catalyst.
Sign Up to like & getrecommendations! Published in 2017 at "ChemSusChem"
DOI: 10.1002/cssc.201601269
Abstract: The reaction mechanism of glycerol hydrogenolysis to 1,2-propanediol over a spinel CuCr2 O4 catalyst was investigated by using DFT calculations. Theoretical models were developed from the results of experimental characterization. Adsorption configurations and energetics of… read more here.
Keywords: cucr2; surface; glycerol hydrogenolysis; reaction ... See more keywords
Combination of DOSY and 1D selective gradient TOCSY: Versatile NMR tools for identify the mixtures from glycerol hydrogenolysis reaction
Sign Up to like & getrecommendations! Published in 2018 at "Fuel Processing Technology"
DOI: 10.1016/j.fuproc.2017.11.011
Abstract: Abstract Hydrogenolysis is necessary for preparing various value-added chemicals from glycerol. Routine methods like GC and HPLC are not sufficient for analysis the reaction mixtures because the products usually have high boiling or similar polarity,… read more here.
Keywords: selective gradient; gradient tocsy; glycerol hydrogenolysis; reaction ... See more keywords
Quantifying the dominant factors in Cu catalyst deactivation during glycerol hydrogenolysis
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Industrial and Engineering Chemistry"
DOI: 10.1016/j.jiec.2017.05.040
Abstract: Abstract Long term stability of a commercial Cu-based glycerol hydrogenolysis catalyst has been studied in an isothermal trickle-bed reactor at 473–503 K in the presence of impurities, such as S, Cl and glycerides. While glycerides have… read more here.
Keywords: deactivation; dominant factors; quantifying dominant; glycerol hydrogenolysis ... See more keywords
Experimental and computational study on roles of WOx promoting strong metal support promoter interaction in Pt catalysts during glycerol hydrogenolysis
Sign Up to like & getrecommendations! Published in 2021 at "Scientific Reports"
DOI: 10.1038/s41598-020-79764-3
Abstract: Biodiesel is of high interest due to increased demand for energy with the concern regarding more sustainable production processes. However, an inevitable by-product is glycerol. Hence, the conversion of this by-product to higher-value chemicals, especially… read more here.
Keywords: promoter; metal support; glycerol hydrogenolysis; interaction ... See more keywords
Artificial intelligence pathway search to resolve catalytic glycerol hydrogenolysis selectivity
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc02107b
Abstract: The complex interaction between molecules and catalyst surfaces leads to great difficulties in understanding and predicting the activity and selectivity in heterogeneous catalysis. Here we develop an end-to-end artificial intelligence framework for the activity prediction… read more here.
Keywords: reaction; energy; glycerol hydrogenolysis; search ... See more keywords
Co-Production of Ethanol and 1,2-Propanediol via Glycerol Hydrogenolysis Using Ni/Ce–Mg Catalysts: Effects of Catalyst Preparation and Reaction Conditions
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DOI: 10.3390/catal7100290
Abstract: Crude glycerol from biodiesel production is a biobased material capable of co-producing biofuels and chemicals. This study aimed to develop a line of Ni catalysts supported on cerium–magnesium (Ce–Mg) to improve the process efficiency of… read more here.
Keywords: pdo; production; glycerol; ethanol pdo ... See more keywords