Articles with "glycidol acetal" as a keyword



Photo from wikipedia

Highly Regio- and Stereoselective Intramolecular Rearrangement of Glycidol Acetal to Alkoxy Cyclic Acetals.

Sign Up to like & get
recommendations!
Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c02397

Abstract: A new class of highly regio- and stereoselective intramolecular rearrangements of glycidol acetals to produce alkoxylated 1,3-dioxolane/1,3-dioxane is demonstrated. Selective Lewis acid activation of acetal generates an oxocarbenium ion that initiates the epoxide ring-opening event,… read more here.

Keywords: intramolecular rearrangement; rearrangement glycidol; glycidol acetal; regio stereoselective ... See more keywords