Synthesis of Poly(glycidyl 2-ylidene-acetate) and Functionalization by Nucleophilic Ring-Opening Reactions
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DOI: 10.1021/acs.macromol.6b02465
Abstract: Rhodium-mediated C1 polymerization of glycidyl 2-diazoacetate resulted in the novel functional polymethylene poly(glycidyl 2-ylidene-acetate), the first functional polymethylene suitable for a subsequent controlled post-polymerization modification at moderate reaction conditions via nucleophilic ring-opening of the epoxide.… read more here.
Keywords: ring opening; glycidyl ylidene; poly glycidyl; nucleophilic ring ... See more keywords