C(sp3)-H/C(sp3)-H Dehydrogenative Radical Coupling of Glycine Derivatives.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02951
Abstract: Here we report a general C(sp3)-H/C(sp3)-H dehydrogenative coupling strategy for the preparation of various natural or unnatural amino acids from readily available glycine derivatives and hydrocarbons through a combination of SET and HAT process. read more here.
Keywords: sp3 dehydrogenative; sp3 sp3; glycine derivatives; radical coupling ... See more keywords
Visible-light-induced Csp3-H functionalization of glycine derivatives by cerium catalysis.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc07071e
Abstract: A Ce(III)-catalyzed, visible-light-induced aerobic oxidative dehydrogenative coupling/aromatization reaction between glycine derivatives and alkenes has been developed, which provides an efficient approach for the synthesis of quinoline derivatives and post-modification of oligopeptides containing glycine residues under… read more here.
Keywords: light induced; induced csp3; glycine; glycine derivatives ... See more keywords