Catalytic Gas‐Phase Cyclization of Glycolate Esters: A Novel Route Toward Glycolide‐Based Bioplastics
Sign Up to like & getrecommendations! Published in 2018 at "ChemCatChem"
DOI: 10.1002/cctc.201801469
Abstract: A catalytic process to produce glycolide, the cyclic dimer of glycolic acid (GA), is proposed. Glycolide is the key building block of the biodegradable plastic polyglycolic acid. Instead of the current industrial two‐step route, which… read more here.
Keywords: glycolide; cyclization; glycolate; gas phase ... See more keywords
Balancing the carbon flux distributions between the TCA cycle and glyoxylate shunt to produce glycolate at high yield and titer in Escherichia coli.
Sign Up to like & getrecommendations! Published in 2018 at "Metabolic engineering"
DOI: 10.1016/j.ymben.2018.02.008
Abstract: The glyoxylate shunt is a branch of the tricarboxylic acid (TCA) cycle which directly determines the synthesis of glycolate, and the balance between the glyoxylate shunt and TCA cycle is very important for the growth… read more here.
Keywords: tca cycle; yield; glycolate; glyoxylate shunt ... See more keywords
Synthesis and Characterization of Micro/Nanoscale VO2(M) through Vanadylethylene Glycolate Decomposition.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c01786
Abstract: Thanks to a homemade dynamic vacuum system, fully crystallized VO2 (M) is successfully synthesized in a merged step of vanadyl ethylene glycolate (VEG) decomposition and crystallization of VO2 at high temperatures (>500 °C). During the… read more here.
Keywords: micro nanoscale; nanoscale vo2; glycolate; characterization micro ... See more keywords
Glycolate Induces Redox Tuning Of Photosystem II in Vivo: Study of a Photorespiration Mutant1
Sign Up to like & getrecommendations! Published in 2018 at "Plant Physiology"
DOI: 10.1104/pp.18.00341
Abstract: Glycolate accumulated in a photorespiration mutant replaces the bicarbonate on the acceptor-side iron of PSII, lowering the yield of singlet oxygen by redox tuning the primary quinone. Bicarbonate removal from the nonheme iron at the… read more here.
Keywords: iron; redox tuning; photosystem; photorespiration ... See more keywords
Poly(Butylene Adipate/Terephthalate-Co-Glycolate) Copolyester Synthesis Based on Methyl Glycolate with Improved Barrier Properties: From Synthesis to Structure-Property
Sign Up to like & getrecommendations! Published in 2022 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms231911074
Abstract: The main problem of manufacturing with traditional biodegradable plastics is that it is more expensive than manufacturing with polymers derived from petroleum, and the application scope is currently limited due to poor comprehensive performance. In… read more here.
Keywords: poly butylene; copolyester; terephthalate; barrier ... See more keywords
In-Operando Diffraction and Spectroscopic Evaluation of Pure, Zr-, and Ce-Doped Vanadium Dioxide Thermochromic Films Derived via Glycolate Synthesis
Sign Up to like & getrecommendations! Published in 2020 at "Nanomaterials"
DOI: 10.3390/nano10122537
Abstract: Pure and doped vanadia (VO2, V0.98Zr0.02O2, V0.98Ce0.02O2) samples were prepared by wet chemistry synthesis from vanadyl glycolate intermediate phase and tape casted into films. Combining in-operando grazing incidence synchrotron X-ray diffraction and Raman spectroscopy, we… read more here.
Keywords: pure; diffraction; spectroscopic; pure doped ... See more keywords