Preparation of glycosyl disulfides and sulfides via the formation of glycosyl Bunte salts as thiol surrogates
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DOI: 10.1016/j.tet.2021.132242
Abstract: Abstract A convenient odourless reaction condition has been developed for the preparation of symmetrical glycosyl disulfide derivatives and aryl glycosyl disulfide derivatives from corresponding glycosyl iodides via in situ formation of glycosyl Bunte salts as… read more here.
Keywords: bunte; salts thiol; bunte salts; formation glycosyl ... See more keywords
Efficient generation of thiolate sugars from glycosyl Bunte salts and its application to S-glycoside synthesis
Sign Up to like & getrecommendations! Published in 2020 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2020.152198
Abstract: Abstract A one-pot aqueous solution method for synthesis of S-glycoside derivatives has been developed. Firstly, unprotected sugars were converted into glycosyl Bunte salts from which thiolate sugars can be generated efficiently using Na2S. The subsequent… read more here.
Keywords: glycosyl bunte; efficient generation; bunte salts; thiolate sugars ... See more keywords