Synthesis of Glycosyl Azides and Their Applications Using CuAAC Click Chemistry to Generate Bis- and Tris(triazolyl)glycosyl Derivatives
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DOI: 10.1055/s-0036-1589090
Abstract: 2,3-Unsaturated C -(triazolyl)glycosyl acetates have been synthesized from 3,4,6-tri- O -acetyl- d -glucal using C -glycosylation and click chemistry and were then used in a palladium-catalyzed Tsuji–Trost type allylic azidation reaction to afford the corresponding… read more here.
Keywords: cuaac; glycosyl derivatives; chemistry; triazolyl glycosyl ... See more keywords
Biological Catalysis and Information Storage Have Relied on N-Glycosyl Derivatives of β-D-Ribofuranose since the Origins of Life
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DOI: 10.3390/biom13050782
Abstract: Most naturally occurring nucleotides and nucleosides are N-glycosyl derivatives of β-d-ribose. These N-ribosides are involved in most metabolic processes that occur in cells. They are essential components of nucleic acids, forming the basis for genetic… read more here.
Keywords: information; glycosyl derivatives; life; information storage ... See more keywords