General Strategy for Stereoselective Synthesis of β- N-Glycosyl Sulfonamides via Palladium-Catalyzed Glycosylation.
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DOI: 10.1021/acs.orglett.8b01506
Abstract: A highly efficient and mild glycosylation reaction between 3,4- O-carbonate glycal and N-tosyl functionalized aliphatic and aromatic amines via palladium-catalyzed decarboxylative allylation is disclosed. A wide range of highly functionalized 2,3-unsaturated β- N-glycosides are furnished… read more here.
Keywords: glycosyl sulfonamides; via palladium; palladium catalyzed; glycosylation ... See more keywords