Probing borafluorene B-C bond insertion with gold acetylide and azide.
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DOI: 10.1039/d2dt03672j
Abstract: The reaction of Ph3PAuN3 with 9-Ph-9-borafluorene resulted in complexation of the azide to boron while a gold acetylide reacted with 9-Ph-9-borafluorene to insert the acetylide carbon to access a six-membered boracycle with an exocyclic double… read more here.
Keywords: bond insertion; borafluorene bond; probing borafluorene; gold ... See more keywords