A stable gold(i)-enyne species obtained by alkyne carboauration in a complex rearrangement.
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DOI: 10.1039/c7cc03713a
Abstract: An unprecedented tetranuclear gold derivative with unusual gold-enyne moieties is prepared by a mild and neat rearrangement of a dinuclear gold complex with a bridging bis(diphenylphosphino)alkyne and terminal alkynyl ligands. The complex originates as a… read more here.
Keywords: rearrangement; gold enyne; gold; triple bond ... See more keywords