Triethylamine Solution for the Intractability of Aqueous Gold–Thiolate Cluster Anions: How Ion Pairing Enhances ESI-MS and HPLC of aq-Aun(pMBA)p
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DOI: 10.1021/acs.jpcc.6b12073
Abstract: Herein we disclose methods that greatly improve the solution- and gas-phase handling properties of larger aqueous-phase gold–thiolate clusters, which previously presented extreme technical obstacles to molecular analysis and size control, even as they have enjoyed… read more here.
Keywords: phase; gold thiolate; solution; ion ... See more keywords
Odd-even effect of the number of free valence electrons on the electronic structure properties of gold-thiolate clusters
Sign Up to like & getrecommendations! Published in 2018 at "Molecular Physics"
DOI: 10.1080/00268976.2018.1554864
Abstract: ABSTRACT It is essential to understand the intrinsic stability of the gold-thiolate clusters, which present extensive potential applications in many fields such as the catalysis, biomedicines and molecular machines. The electronic structures and aromaticity indexes… read more here.
Keywords: even effect; gold thiolate; odd even; structure ... See more keywords