Engineering 3d–2p–4f Gradient Orbital Coupling to Enhance Electrocatalytic Oxygen Reduction
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202206540
Abstract: The development of highly efficient and economical materials for the oxygen reduction reaction (ORR) plays a key role in practical energy conversion technologies. However, the intrinsic scaling relations exert thermodynamic inhibition on realizing highly active… read more here.
Keywords: oxygen reduction; engineering gradient; gradient orbital; orbital coupling ... See more keywords
Reinforce the Co-O Covalency via Ce(4f)-O(2p)-Co(3d) Gradient Orbital Coupling for High-efficiency Oxygen Evolution.
Sign Up to like & getrecommendations! Published in 2023 at "Advanced materials"
DOI: 10.1002/adma.202302462
Abstract: Rare-earth (RE)-based transition metal oxides (TMO) are emerging as a frontier towards oxygen evolution reaction (OER), yet the knowledge regarding their electrocatalytic mechanism and active sites is very limited. Herein, we successfully design and synthesize… read more here.
Keywords: gradient orbital; oxygen evolution; spectroscopy; coo ... See more keywords