Noncovalently connected supramolecular metathesis graft copolymers: One-pot synthesis and self-assembly
Sign Up to like & getrecommendations! Published in 2019 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2018.10.032
Abstract: Abstract For the first time, noncovalently connected supramolecular polymers were prepared by ring-opening metathesis polymerization (ROMP) and host–guest interactions in a one-pot process. An adamantane-based oxanorbornene dicarboximide derivative was first prepared, and then ROMP was… read more here.
Keywords: connected supramolecular; noncovalently connected; metathesis; graft copolymers ... See more keywords
Synthesis of polyethylene-g-polydimethylsiloxane graft copolymers by copolymerization of ethylene with polydimethylsiloxane macromonomer
Sign Up to like & getrecommendations! Published in 2019 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2019.06.016
Abstract: Abstract This paper discusses the synthesis of polyethylene-g-polydimethylsiloxane (PE-g-PDMS) graft copolymers through a facile macromonomer approach. A novel octene-terminated PDMS macromonomer was synthesized via anionic ring-opening polymerization of hexamethylcyclortrisiloxane and the subsequent chain-end capping with… read more here.
Keywords: synthesis polyethylene; polyethylene polydimethylsiloxane; macromonomer; graft copolymers ... See more keywords
Tributylborane in the synthesis of graft-copolymers of gelatin and acrylamide
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121431
Abstract: Abstract Tributylborane in different concentrations was used for synthesis of gelatin and polyacrylamide graft-copolymer. The copolymers were characterized by Fourier transform infrared spectroscopy method (FTIR). The share of the graft polyacrylamide and the molecular weight… read more here.
Keywords: graft copolymers; graft; synthesis graft; tributylborane synthesis ... See more keywords
Quantitative Grafting for Structure-Function Establishment: Thermoresponsive Poly(alkylene oxide) Graft Copolymers Based on Hyaluronic Acid and Carboxymethylcellulose.
Sign Up to like & getrecommendations! Published in 2019 at "Biomacromolecules"
DOI: 10.1021/acs.biomac.8b01692
Abstract: A series of thermoresponsive graft copolymers, gelling at physiological conditions in aqueous solution and cell growth media, have been synthesized using quantitative coupling between a small set of amino-functionalized poly(alkylene oxide) copolymers (PAO) and the… read more here.
Keywords: graft; graft copolymers; poly alkylene; function ... See more keywords
Polyampholytic Poly(dehydroalanine) Graft Copolymers as Smart Templates for pH-Controlled Formation of Alloy Nanoparticles
Sign Up to like & getrecommendations! Published in 2020 at "Macromolecules"
DOI: 10.1021/acs.macromol.0c00474
Abstract: Polymer templates are a facile way to control the formation, size, and shape of different inorganic nanomaterials by tuning solution behavior, morphology, or density and the type of functional grou... read more here.
Keywords: smart templates; poly dehydroalanine; graft copolymers; polyampholytic poly ... See more keywords
Viscoelastic Properties of Hydrogels Based on Self-Assembled Multisticker Polymers Grafted with pH-Responsive Grafts
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecules"
DOI: 10.1021/acs.macromol.7b01585
Abstract: Graft copolymers consisting of a poly(acrylic acid) (PAA) backbone and random grafts of n-butyl acrylate and acrylic acid, P(nBA50%-stat-AA50%)100, were synthesized by free radical polymerization of the backbone followed by ATRP polymerization of the grafts… read more here.
Keywords: based self; graft copolymers; self assembled; hydrogels based ... See more keywords
Synthesis of Highly Defined Graft Copolymers Using a Cyclic Acetal Moiety as a Two-Stage Latent Initiating Site for Successive Living Cationic Polymerization and Ring-Opening Anionic Polymerization
Sign Up to like & getrecommendations! Published in 2018 at "Macromolecules"
DOI: 10.1021/acs.macromol.7b02622
Abstract: The synthesis of well-defined graft copolymers with designed intervals between branches was achieved using cyclic acetal moieties as two-stage latent initiating sites. A cyclic acetal was shown to initiate the living cationic polymerization of vinyl… read more here.
Keywords: cyclic acetal; cationic polymerization; polymerization; graft copolymers ... See more keywords
UV-responsive amphiphilic graft copolymers based on coumarin and polyoxazoline.
Sign Up to like & getrecommendations! Published in 2017 at "Soft matter"
DOI: 10.1039/c7sm00682a
Abstract: A series of amphiphilic photo-responsive heterografted copolymers have been successfully synthesized. The random copolymers were composed of a methacrylate backbone, with various compositions of hydrophilic oligomeric 2-methyl-2-oxazoline side chains (OMOx) and hydrophobic long alkyl chains… read more here.
Keywords: based coumarin; graft copolymers; responsive amphiphilic; copolymers based ... See more keywords
Metal-free ATRP “grafting from” technique for renewable cellulose graft copolymers
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DOI: 10.1039/c9gc00138g
Abstract: Photoinduced metal-free “grafting from” atom transfer radical polymerization (ATRP) has been successfully applied to the fabrication of renewable cellulose graft copolymers with the aid of 2-bromo-2-phenylacetyl ester-modified ethyl cellulose as the macroinitiator. read more here.
Keywords: cellulose graft; graft copolymers; metal free; atrp ... See more keywords
Polyolefin graft copolymers through a ring-opening metathesis grafting through approach
Sign Up to like & getrecommendations! Published in 2021 at "Polymer Chemistry"
DOI: 10.1039/d0py01728k
Abstract: A series of polyethylene-g-atactic polypropylene graft copolymers were synthesized by grafting through copolymerization of a cyclooctene terminated aPP macromonomer with cyclooctene monomer and subsequent hydrogenation. read more here.
Keywords: copolymers ring; graft copolymers; polyolefin graft; opening metathesis ... See more keywords
Atypical vesicles and membranes with monolayer and multilayer structures formed by graft copolymers with diblock side-chains: nonlamellar structures and curvature-enhanced permeability.
Sign Up to like & getrecommendations! Published in 2022 at "Soft matter"
DOI: 10.1039/d2sm01055k
Abstract: Graft copolymers with diblock side-chains Am(-graft-B3Ay)n in a selective solvent have been reported to self-assemble into vesicles, but the structure is expected to differ distinctly from those of lipid bilayers. Surprisingly, the number of alternating… read more here.
Keywords: graft copolymers; copolymers diblock; side chains; side ... See more keywords