Metal‐free ATRP and ROP for graft copolymers: an orthogonal strategy for sequential and concurrent polymerizations at room temperature
Sign Up to like & getrecommendations! Published in 2025 at "Polymer International"
DOI: 10.1002/pi.70031
Abstract: Well‐defined poly[(methyl acrylate)‐co‐(hydroxyethyl acrylate)]‐graft‐ poly(ε‐caprolactone ) copolymers were synthesized using a completely metal‐free strategy by combining atom transfer radical polymerization (ATRP) and ring‐opening polymerization (ROP) at ambient temperature. These two orthogonal, metal‐free, controlled/living processes, tested… read more here.
Keywords: metal free; graft; strategy; graft copolymers ... See more keywords
Advancements in Biopolymer‐Derived Graft Copolymers: A Comprehensive Review on Their Application in Sustainable Wastewater Treatment
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DOI: 10.1002/tqem.22320
Abstract: Rising concerns over water pollution and the depletion of non‐renewable resources have propelled the exploration of eco‐friendly and sustainable wastewater treatment alternatives. Biopolymer‐derived graft copolymers emerge as a promising solution, offering biodegradability, cost‐effectiveness, versatility, and… read more here.
Keywords: treatment; wastewater treatment; derived graft; biopolymer derived ... See more keywords
Noncovalently connected supramolecular metathesis graft copolymers: One-pot synthesis and self-assembly
Sign Up to like & getrecommendations! Published in 2019 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2018.10.032
Abstract: Abstract For the first time, noncovalently connected supramolecular polymers were prepared by ring-opening metathesis polymerization (ROMP) and host–guest interactions in a one-pot process. An adamantane-based oxanorbornene dicarboximide derivative was first prepared, and then ROMP was… read more here.
Keywords: connected supramolecular; noncovalently connected; metathesis; graft copolymers ... See more keywords
Synthesis of polyethylene-g-polydimethylsiloxane graft copolymers by copolymerization of ethylene with polydimethylsiloxane macromonomer
Sign Up to like & getrecommendations! Published in 2019 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2019.06.016
Abstract: Abstract This paper discusses the synthesis of polyethylene-g-polydimethylsiloxane (PE-g-PDMS) graft copolymers through a facile macromonomer approach. A novel octene-terminated PDMS macromonomer was synthesized via anionic ring-opening polymerization of hexamethylcyclortrisiloxane and the subsequent chain-end capping with… read more here.
Keywords: synthesis polyethylene; polyethylene polydimethylsiloxane; macromonomer; graft copolymers ... See more keywords
Tributylborane in the synthesis of graft-copolymers of gelatin and acrylamide
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121431
Abstract: Abstract Tributylborane in different concentrations was used for synthesis of gelatin and polyacrylamide graft-copolymer. The copolymers were characterized by Fourier transform infrared spectroscopy method (FTIR). The share of the graft polyacrylamide and the molecular weight… read more here.
Keywords: graft copolymers; graft; synthesis graft; tributylborane synthesis ... See more keywords
Quantitative Grafting for Structure-Function Establishment: Thermoresponsive Poly(alkylene oxide) Graft Copolymers Based on Hyaluronic Acid and Carboxymethylcellulose.
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DOI: 10.1021/acs.biomac.8b01692
Abstract: A series of thermoresponsive graft copolymers, gelling at physiological conditions in aqueous solution and cell growth media, have been synthesized using quantitative coupling between a small set of amino-functionalized poly(alkylene oxide) copolymers (PAO) and the… read more here.
Keywords: graft; graft copolymers; poly alkylene; function ... See more keywords
Polyampholytic Poly(dehydroalanine) Graft Copolymers as Smart Templates for pH-Controlled Formation of Alloy Nanoparticles
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DOI: 10.1021/acs.macromol.0c00474
Abstract: Polymer templates are a facile way to control the formation, size, and shape of different inorganic nanomaterials by tuning solution behavior, morphology, or density and the type of functional grou... read more here.
Keywords: smart templates; poly dehydroalanine; graft copolymers; polyampholytic poly ... See more keywords
Viscoelastic Properties of Hydrogels Based on Self-Assembled Multisticker Polymers Grafted with pH-Responsive Grafts
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecules"
DOI: 10.1021/acs.macromol.7b01585
Abstract: Graft copolymers consisting of a poly(acrylic acid) (PAA) backbone and random grafts of n-butyl acrylate and acrylic acid, P(nBA50%-stat-AA50%)100, were synthesized by free radical polymerization of the backbone followed by ATRP polymerization of the grafts… read more here.
Keywords: based self; graft copolymers; self assembled; hydrogels based ... See more keywords
Synthesis of Highly Defined Graft Copolymers Using a Cyclic Acetal Moiety as a Two-Stage Latent Initiating Site for Successive Living Cationic Polymerization and Ring-Opening Anionic Polymerization
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DOI: 10.1021/acs.macromol.7b02622
Abstract: The synthesis of well-defined graft copolymers with designed intervals between branches was achieved using cyclic acetal moieties as two-stage latent initiating sites. A cyclic acetal was shown to initiate the living cationic polymerization of vinyl… read more here.
Keywords: cyclic acetal; cationic polymerization; polymerization; graft copolymers ... See more keywords
One-Step Radical-Induced Synthesis of Graft Copolymers for Effective Compatibilization of Polyethylene and Polypropylene.
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DOI: 10.1021/jacs.5c03869
Abstract: The synthesis of copolymers from high-density polyethylene (HDPE) and isotactic polypropylene (iPP) has gained increasing attention due to their ability to improve the recycling of incompatible mixed polyolefin waste feed streams. Herein, we report a… read more here.
Keywords: hdpe ipp; synthesis; polyethylene; compatibilization ... See more keywords
UV-responsive amphiphilic graft copolymers based on coumarin and polyoxazoline.
Sign Up to like & getrecommendations! Published in 2017 at "Soft matter"
DOI: 10.1039/c7sm00682a
Abstract: A series of amphiphilic photo-responsive heterografted copolymers have been successfully synthesized. The random copolymers were composed of a methacrylate backbone, with various compositions of hydrophilic oligomeric 2-methyl-2-oxazoline side chains (OMOx) and hydrophobic long alkyl chains… read more here.
Keywords: based coumarin; graft copolymers; responsive amphiphilic; copolymers based ... See more keywords