High-Yield Alkylation and Arylation of Graphene via Grignard Reaction with Fluorographene
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.6b05040
Abstract: C functionalization of graphene significantly broadens its application potential via tuning its electronic and surface properties. Therefore, a wide range of dry and wet chemistry approaches have been developed for graphene functionalization. Despite recent progress… read more here.
Keywords: high yield; graphene; chemistry; grignard reaction ... See more keywords
The Grignard Reaction-Unraveling a Chemical Puzzle.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b11829
Abstract: More than one hundred years since its discovery, the mechanism of the Grignard reaction remains unresolved. Ambiguities arise from the concomitant presence of multiple organomagnesium species and the competing mechanisms involving either nucleophilic addition or… read more here.
Keywords: chemical puzzle; unraveling chemical; grignard reaction; reaction ... See more keywords
Barbier polymerization induced emission of cinnamaldehyde: a one-pot Grignard reaction?
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04902c
Abstract: The Barbier reaction is generally regarded as a one-pot Grignard reaction. Here, the Grignard reaction of cinnamaldehyde is demonstrated to give a 1,2-addition product, while the Barbier reaction of cinnamaldehyde yields a macromolecule with interesting… read more here.
Keywords: reaction; grignard reaction; pot grignard; one pot ... See more keywords