Grignard Reagent Mediated Demetallation of Silver Corrole Complexes
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201601549
Abstract: Abstract: In order to study the reactivity of various Grignard reagents with differently substituted A3− and trans-A2B-corrolato Ag (III) complexes, we have performed a series of reactions. We have observed that among the various Grignard… read more here.
Keywords: silver corrole; reagent mediated; demetallation silver; mediated demetallation ... See more keywords
Progressive freezing and suspension crystallization methods for tetrahydrofuran recovery from Grignard reagent wastewater
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Cleaner Production"
DOI: 10.1016/j.jclepro.2017.01.012
Abstract: Abstract Freezing methods, progressive freezing and suspension crystallization, were examined for treating Grignard reagent wastewater containing tetrahydrofuran (THF) used as a solvent. The effect of freezing temperature, addition of seed ice crystals, and stirring speed… read more here.
Keywords: suspension crystallization; seed; progressive freezing; wastewater ... See more keywords
Redox behavior of VS2 nanosheets in Grignard reagent-based electrolyte
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DOI: 10.1016/j.matlet.2020.127914
Abstract: Abstract The redox behavior of VS2 nanosheets in Grignard reagent-based Mg2+ electrolytes was investigated, establishing that VS2 nanosheets functioned as an electrochemical capacitor. Bulk VS2 was synthesized hydrothermally and exfoliated under ultrasonication. Following exfoliation, the… read more here.
Keywords: behavior vs2; reagent based; vs2 nanosheets; redox behavior ... See more keywords
Grignard reagent formation via C-F bond activation: a centenary perspective.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06753b
Abstract: Examples of Grignard reagents obtained by C-F bond activation with magnesium have kept appearing in the literature over the last century. Due to the high bond dissociation energy of the C-F bond, a lot of… read more here.
Keywords: reagent formation; magnesium; bond activation; grignard reagent ... See more keywords