Triazene as the Directing Group Achieving Highly Ortho-Selective Diborylation and Sequential Functionalization.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00994
Abstract: This study describes a regioselective ortho,ortho'-diborylation of aromatic triazenes catalyzed by [Ir(OMe)(cod)]2 in near-quantitative yields without an additional ligand. Aromatic triazenes act as both substrates and ligands. The X-ray structures of 2a and 2p indicate… read more here.
Keywords: group achieving; diborylation; triazene directing; achieving highly ... See more keywords