Migratory insertion of bis(diethylamino)phosphine group into the N–N bond in the reaction of substituted hydrazobenzene with (Et2N)2PCl
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DOI: 10.1007/s11172-020-2734-6
Abstract: Oxidative dehydrogenation of 2-bromo-4-methylaniline with manganese(iv) oxide leads to the formation of (E)-1,2-bis(2-bromo-4-methylphenyl)diazene (1). The reaction of 1 with hydrazine hydrate gives the reduction product, 1,2-bis(2-bromo-4-methylphenyl)hydrazine (2). Compound 2 sequentially treated with methyllithium and two… read more here.
Keywords: et2n 2pcl; migratory insertion; bis; reaction ... See more keywords